Chloride stress corrosion cracking cscc is a type of intergranular corrosion. A phenomenological study was undertaken of the stress corrosion cracking scc of type 304l uns s30403 austenitic stainless steel ss in boiling 44 wt% magnesium chloride mgcl 2 aqueous solution. While the surveyed studies all explore scc of austenitic stainless steels under atmospheric. May 27, 2011 for austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. Stress corrosion cracking of type 304l stainless steel in. Stress corrosion cracking scc refers to cracking of a susceptible material caused by the simultaneous presence of tensile stress and a specific corrosive medium. The decay heat of the spent nuclear fuel in dry storage, by design, will dissipate through the stainless steel canister via natural convection. Austenitic stainless steels sss and aqueous chloride environment represent one such combination of. Stress corrosion cracking susceptibility of 304l substrate and. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. As expected the asreceived 304l stainless steel was susceptible to stress corrosion cracking.
Chloride induced stress corrosion cracking of type 304 and 304l. The combination of susceptible material and the specific corrosive medium is critical in inducing scc 1,2. Electrochemical studies were made in aqueous licl, mgcl 2, and mgbr 2 solutions and in zncl 2 kcl molten salt to clarify the corrosion reactions related to stress corrosion cracking scc of austenitic stainless steel and to better define environmental variables critical to the occurrence of chloride scc. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Stress corrosion cracking of laser alloyed 304l stainless. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Pdf chloride induced stress corrosion cracking of type 304. Transgranular stress corrosion cracking of 304l stainless. Chlorides simulating sea salt particles were put on the gage section of the ss as droplets of synthetic sea water. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Because many of the dry storage containers are made of austenitic stainless steels, a potential concern is the susceptibility of the canisters to undergo chloride induced stress corrosion cracking. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316.
Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Three underlying factors must be present to cause scc. Failure of stainless steel 304l air cooler tubes due to. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. Susceptible alloys include 304l, 316l, 321, and 347. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions. An example is hot potable water under heat transfer conditions which permit chlorides to concentrate locally. The standard 304 304l and 316316l grades are most susceptible. Proceedings of the asme 2008 pressure vessels and piping conference. Finite element modelling of transgranular chloride stress corrosion cracking in 304l austenitic stainless steel. Chlorideinduced stress corrosion cracking of 316 stainless. However, molybdenum itself does not get incorporated in the passive film.
Nuregcr7030, atmospheric stress corrosion cracking. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. This study evaluated the stress corrosion cracking scc susceptibility of asreceived and sensitized uns s30400 stainless steel exposed to ammonium nitrate mixed with sodium chloride salts. Methods of minimizing chloride stress corrosion cracking. Influence of high temperature on corrosion behavior of 304. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Pdf stress corrosion cracking of austenitic stainless. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc.
A systematic study of the effect of cold work cw on chloride induced stress corrosion cracking scc in 304l stainless steel was performed. This together with slightly higher stacking fault energy schramm and reed 1975 are the main reasons for better resistance of type 316316l stainless steel than type 304 304l to stress corrosion cracking in sodium chloride solutions. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Mechanism of chloride stress corrosion cracking of. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Although no stainless steel grade is totally immune to chloride scc, the relative. Duplex grades are usually divided into three subgroups based on their corrosion resistance. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stress corrosion cracking susceptibility of 304l substrate.
Bending tests were used to investigate the stresscorrosion cracking of 304l stainless steel in a corrosive atmosphere containing magnesium chloride. Chloride induced stress corrosion cracking of type 304 and. Different kinds of corrosion on stainless steel montanstahl. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. Effects of marine environments on stress corrosion. The alloys are used widely in equipment and utensils for processing and handling of food, beverages, and dairy products. Design guidelines for the selection and use of stainless steel nidl distributed by.
Effects of marine environments on stress corrosion cracking. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. Assessing the risk of underdeposit chloride induced stress corrosion cracking in austenitic stainless steel nuclear waste containers. Stress corrosion cracking scc is a common issue with many specialty alloys. Some 95% of 316l chemical plant equipment failures may be attributed to chloride scc. The decay heat of the spent nuclear fuel in dry storage, by design, will dissipate through the stainless steel.
In all cases of failure by stress corrosion cracking, the following three factors must be present. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Sensor requirements for detection and characterization of. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chlorideinduced stress corrosion cracking at ambient temperature of 304l austenitic stainless. Mechanism of chloride stress corrosion cracking of austenitic. Sep 21, 2018 there is also a problem with stress corrosion cracking in temperatures greater than 60 c.
Therefore, standard grades such as 304304l and 316316l are very. Thierry, lowtemperature stress corrosion cracking of stainless steels in the. General corrosion the alloys 304, 304l, and 304h austenitic stainless steel provide useful resistance to corrosion on a wide range of moderately oxidizing to moderately reducing environments. Duplex stainless steel improved corrosion and more importantly, stress corrosion cracking resistance higher strength and hardness. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization.
What is the maximum chloride in ppm that can be allowed in. Chloride induced stress corrosion cracking ciscc is a significant problem. Seawater, in particular, can have a detrimental effect on the longevity of the metal, and this is the main difference between it and 316 stainless steel. Cw between 0% and 40% was applied prior to corrosion of specimens at 75 c and 70% relative humidity, for 500 h, using mgcl 2 at atmospheric pressure. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chloride induced stress corrosion cracking at ambient temperature of 304l austenitic stainless. To that end, types 304, 304l, and 316l stainless steel ubend samples were fabricated and placed in an environmental chamber. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The objective of this work is to evaluate if atmospheric stress corrosion cracking can develop in stainless steel cask. Corrosion pits act as stress concentrators to initiate scc in.
Stress corrosion cracking of uns s30400 stainless steel. This mode of attack is termed stress corrosion cracking scc. Finite element modelling of transgranular chloride stress. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Also ss 304l has any mo about 2 to 3%, if not then try ss 304l with. Chloride stress corrosion cracking in austenitic stainless. Stress corrosion cracking of sensitized type 304 stainless. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Stress corrosion cracking of laser alloyed 304l stainless steel with. Transgranular stress corrosion cracking of 304l stainless steel pipe clamps in direct use geothermal water heating applications michael f. With the addition of ru to 304l stainless steel, the resistance to cracking improved markedly, the minimum and maximum crack propagation rate attained was 0.
What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Initiation and propagation of stress corrosion cracking of. Scc can occur typically in hot water tanks or swimming pools. Chloride stress corrosion cracking and 316 stainless steel chloride stress corrosion cracking and 316 stainless steel beh188 mechanical op 19 jul 11 17. The failure cracks propagated from intergranular pickling damage to the 12inchthick steel, which was sensitized during initial fabrication. Simulated sea salt was deposited on the surface of the samples, using a salt fog procedure.
The effect of prior cold work on the chloride stress. I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. As 304 but with lower carbon content to minimise carbide precipitation during welding. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Wenman, mark, barton, james, trethewey, kenneth, jarman, sean, and chardtuckey, paul. On the stress corrosion cracking and hydrogen embrittlement. Stress corrosion cracking international institute of. Higher levels of chloride might cause crevice corrosion and pitting.
High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Assessing the risk of underdeposit chlorideinduced. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Feb 15, 2017 a great concern for the longterm integrity of canisters located near the coastline is chloride induced stress corrosion cracking of austenitic stainless steels 3,4,5.
Why are austenitic stainless steels more susceptible to chloride stress corrosion cracking than ferritic stainless steels. Type 304 stainless steel electrodes were employed, with complementary. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. This provides improved fatigue and wear resistance higher tensile and yield strength compared to the austenitics translates into thinner walls and less weight which can offset the cost to some extent. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Atmospheric salt fog testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel todd s. Reference is often made to stainless steel in the singular sense as if it were one material. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of.
Chloride oxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Effect of ph and chloride contents on stress corrosion. Deterioration by clscc can lead to failures that have the potential to release. This diagram figure 1 is analogous to a similar diagram for caustic. Intergranular stress corrosion cracking caused failure of two type304 stainless steel outlet nozzles in highpurity heavywater moderator service in nuclear reactors. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of 35 %. Chloride stress corrosion cracking in austenitic stainless steel. Atmospheric chamber testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel. Scc tests were conducted at 45 c44% relative humidity using ubend specimens coated with salt mixtures of ammonium nitrate and sodium chloride with mole.
The objective of the work described in this paper was to further the understanding of atmospheric crack growth rate of stainless steel in a chloride rich environment. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Atmospheric chamber testing to evaluate chloride induced stress. Scc susceptibility of ru laser surface alloyed 304l stainless steel in hot chloride solution.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Chloride stress corrosion cracking and 316 stainless steel. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. From the morphological information available on the specimen surface after constant elongation rate testing cert and taking into account the real crack shapes, initiation could. The effect of salt loading on chlorideinduced stress corrosion cracking of 304l austenitic stainless steel under atmospheric conditions author links open overlay panel g. Summary of available data for estimating chlorideinduced scc. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Chloride stress corrosion cracking inspectioneering. Atmospheric salt fog testing to evaluate chloride induced. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353k with relative humidity rh of 35%. Pdf chloride induced stress corrosion cracking of type. The effect of salt loading on chloride induced stress corrosion cracking in 304 l was studied at atmospheric pressure. Srnl was responsible for conducting corrosion studies in smallscale vessels to address the influence of salt composition, water loading, and type of oxidesalt contact on the relative humidity inside a 30 container and on the resulting corrosion of type 304l and 316l stainless steel 304l and 316l.
Although no stainless steel grade is totally immune. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Mintz1, leonardo caseres2, darrell s dunndarrell s. A great concern for the longterm integrity of canisters located near the coastline is chloride induced stress corrosion cracking of austenitic stainless steels 3,4,5. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. The initiation and propagation of chlorideinduced transgranular. The effect of salt loading on chlorideinduced stress. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl.
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